WebThe efficient one-pot conversion of propargyl alcohols to their saturated carbonyl analogues is carried out for the first time using metal nanoparticle catalysts, dodecanethiolate-capped Pd nanoparticles.Kinetic studies reveal that the reaction progresses through a semi-hydrogenation intermediate (allyl alcohols) followed by isomerization to carbonyls. WebApr 1, 2005 · We have successfully synthesized dodecanethiolate-protected Cu 2 S nanoparticles in a two-phase system. A lower molar ratio of RSH/Cu favors formation of …
Phys. Rev. B 68, 195415 (2003) - Dynamic final-state effect on the …
WebNickel sulfide was formed by thermal decomposition of nickel(II) dodecanethiolate in the high-boiling solvent, and the crystal phases of nickel sulfide were controlled by selection … WebNov 21, 2024 · A lean synthesis of copper nanoparticles (Cu NP) from CuCl 2 in dodecane via formation of Cu(I)-dodecanethiolate (Cu(I)-DDT) and their decomposition paths … proc sql if missing then 0
Photoemission study of metallic nanoparticles passivated by ...
WebApr 1, 2005 · Dodecanethiolate-protected Cu 2 S nanoparticles were synthesized in a two-phase system, and characterized by IR spectroscopy, X-ray photoelectron spectroscopy, Auger Electron Spectra, and transmission electron microscopy.The particle size can be controlled by the molar ratio of dodecanethiol to Cu(OH) x (x−2).An increase of the ratio … WebSilver tert-dodecanethiolate. Regulatory process names 2 IUPAC names 1 Other identifiers 1 . Print infocard. Substance identity Substance identity. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. The substance identifiers displayed in the InfoCard are the best available ... WebOct 17, 2011 · Although it is known that metallic silver can be produced by the thermal decomposition of silver n-dodecanethiolate (Ag-DDT), the use of this reaction to synthesize silver-modified coatings is difficult due to the insolubility of Ag-DDT in most solvents and coating precursors.We report that lamellar Ag-DDT crystals can be … proc sql inner join two variables